• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    membrane filtration with the use of low energy power spacer. it is a membrane filtration element. the element may include at least one feed spacer that includes a first set of parallel filaments that extend in a first direction and that include a plurality of first filaments that have a first thickness and a plurality of second filaments that have a second thickness that is less than the first thickness. a second set of parallel filaments may extend in a second direction that is transverse to the first direction. the second set of parallel filaments may include a plurality of third filaments that have a third thickness and a plurality of fourth filaments that have a fourth thickness that is less than the third thickness. in one embodiment, the first and second sets of filaments include alternating thin and thick filaments, which reduce the pressure drop in membrane filtration systems.
    公开号:BR112014032391B1
    申请号:R112014032391-7
    申请日:2013-06-17
    公开日:2021-08-10
    发明作者:Alexander James Kidwell
    申请人:SWM Luxembourg S.à.R.L.；
    IPC主号:
    专利说明:

    CROSS REFERENCE TO RELATED ORDERS
    [001] This application claims priority to the benefit of provisional application no. U.S. 61/690,419, filed June 26, 2012, the description of which is incorporated herein in its entirety by reference. FIELD OF TECHNIQUE
    [002] The present invention relates to an extruded network for use in membrane filtration, such as reverse osmosis systems. BACKGROUND
    [003] Membrane filtration is a process used to separate a liquid feed, or inlet, into a product stream and a concentrate stream. Typically, the feed stream is water that needs to be filtered or desalinated so that it can be used for drinking, agricultural and industrial applications. In membrane filtration, a membrane acts as a barrier to allow certain compounds to pass through it, while rejecting others. One type of membrane filtration is reverse osmosis (RO) filtration, which is a pressure-driven process. During osmosis, water will diffuse from an area of high solute concentration to an area of low concentration due to osmotic pressure, until an osmotic balance is reached. Reverse osmosis is a process in which pressure is applied to a high concentration volume of solute in order to overcome the osmotic pressure and force water at the high concentration of solute to diffuse through the membrane to a low volume of solute, thus leaving the solute behind. Membranes used in RO filtration are very selective and allow almost no solute to pass through.
    [004] One type of RO filtration system is known as a spiral wound element system. In this system, one or more membrane envelopes are wrapped around an elongated collection tube. Each membrane envelope comprises two outer membrane surfaces and a sheet of permeate between them which communicates with holes in the side wall of the collection tube. A feed spacer is disposed on one side of each membrane envelope such that when the membrane envelope is wrapped around the collection tube, a spiral configuration is formed with alternating layers of membrane envelope and spacer. food. The collection tube, membrane envelope(s) and feed spacer(s) combine to form a spirally wound element. Multiple elements are typically combined in series and parallel to larger volumes of free liquid process.
    [005] In use, the spirally wound element is placed in a pressure vessel and water containing a high concentration of solute (known as feed water) is pumped, under pressure, into one end of the pressure vessel. Feed water enters the spirally wound membrane through the channels between the membrane envelopes created by the feed spacers and moves parallel to the geometric axis of the collection tube. A portion of the feedwater diffuses through the membrane and into the permeate sheet due to the high pressure of the feedwater that exceeds the osmotic pressure. The permeate sheet guides the water in a spiral direction until it reaches the collection tube and subsequently moves axially to the end of the spirally wound element. Feedwater that does not diffuse through the membrane continues to move in the axial direction and is typically transferred to another spiral-wound element connected in series with the first spiral-wound element. SUMMARY
    [006] In at least one embodiment, a spirally wound filtration element is provided comprising a central collection tube having at least one orifice defined therein, at least one membrane envelope attached to the central collection tube and having two sheets of membrane separated by a spacer, the at least one membrane envelope being configured to be wrapped around the central collection tube to form a spiral, and at least one feed spacer configured to be disposed adjacent the at least a sheet of membrane, when wrapped around the central collection tube, and to create a channel to receive the liquid to be filtered. The feed spacer may comprise a net that includes a first set of parallel filaments that extend in a first direction and that includes a plurality of first filaments that have a first thickness and a plurality of second filaments that have a second thickness that is smaller. than the first thickness, and a second set of parallel filaments that extend in a second direction that is transverse to the first direction. The first set of filaments and the second set of filaments can always be located on the same side of each other.
    [007] In at least one embodiment, an extruded net is provided comprising a first set of parallel filaments extending in a first direction and including a plurality of first filaments having a first thickness and a plurality of second filaments having a second thickness that is less than the first thickness, and a second set of parallel filaments that extend in a second direction that is transverse to the first direction and that includes a plurality of third filaments that have a third thickness and a plurality of fourth filaments. which have a fourth thickness that is less than the third thickness. The first set of filaments and the second set of filaments may always be located on the same side of each other, and the first set of parallel filaments may comprise alternate first and second filaments and the second set of parallel filaments may comprise alternate third and fourth filaments.
    [008] In at least one embodiment, a spirally wound filtration element is provided comprising a central collection tube having at least one orifice defined therein, at least one membrane envelope attached to the central collection tube and having two sheets of membrane separated by a spacer, the at least one membrane envelope configured to be wrapped around the central collection tube to form a spiral, and at least one feed spacer disposed adjacent to at least one sheet of membrane when wrapped around the central collection tube, and to create a channel to receive the liquid to be filtered. The feed spacer may comprise a net that includes a first set of parallel filaments that extend in a first direction and that includes a plurality of first filaments that have a first thickness and a plurality of second filaments that have a second thickness that is smaller. that the first thickness, and a second set of parallel filaments that extend in a second direction that is transverse to the first direction and that includes a plurality of third filaments that have a third thickness and a plurality of fourth filaments that have a fourth thickness that is less than the third thickness. The first set of filaments and the second set of filaments can always be located on the same side of each other. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a cutaway view of a reverse osmosis spiral-wound element in accordance with at least one embodiment; Figure 2 is a perspective view of a network, according to at least one embodiment; Figure 3 is a top view of a net, according to at least one embodiment; Figure 4 is a cross-section of a network between adjacent membrane sheets, according to at least one embodiment; Figure 5 is a cross-section of a prior art network between adjacent sheets of membrane; and Figure 6 is a photograph of a cross-section of a network between adjacent membrane sheets, according to at least one embodiment. DETAILED DESCRIPTION
    [009] As required, detailed embodiments of the present invention are disclosed herein; however, it should be understood that the disclosed embodiments are only exemplary of the invention which may be embodied in diverse and alternative ways. Figures are not necessarily to scale; some features can be exaggerated or minimized to show details of particular components. Therefore, the specific functional and structural details disclosed herein are not to be construed as limiting, but only as a representative basis for instructing a person skilled in the art to employ the present invention in a variety of ways.
    [010] Except in the examples, or where expressly stated otherwise, all numerical quantities in this description that indicate quantities of material or conditions of reaction and/or use shall be understood as modified by the term "about" in the broader scope description of the invention. Practice within the numerical limits indicated is generally preferred. In addition, except where expressly stated otherwise: percent, "parts of" and ratio values are by weight; the term "polymer" includes "oligomer", "copolymer", "terpolymer", and the like; the description of a group or class of materials, as suitable or preferred for a particular purpose in connection with the invention, implies that mixtures of any two or more of the members of the group or class are equally suitable or preferred; the description of constituents in chemical terms refers to the constituents at the time of addition to any combination specified in the description, and does not necessarily exclude chemical interactions between the constituents of a mixture once mixed; and the first definition of an acronym or other abbreviation applies to all subsequent uses in this document of the same abbreviation and applies mutatis mutandis to normal grammatical variations of the initially defined abbreviation.
    [011] Referring to Figure 1, a spiral wound element of reverse osmosis (RO) system 1 is shown. Although an RO system is illustrated, the same general configuration is applicable to membrane filtration systems in general. The spirally wound element (the element) 1 is typically configured to be placed in a pressure vessel 2 (not shown). Element 1 comprises at least one membrane envelope 4, which includes two membrane sheets 6 that encapsulate a spacer, generally a permeate sheet 8. The permeate sheet 8 is attached, along one side, to a tube. pickup 10 which has holes 12 spaced in an axial direction. A feed spacer 14 is provided between each membrane envelope 4 such that at least one membrane sheet 6 in each membrane envelope 4 contacts a feed spacer 14. The spirally wound element 1 is formed when the Membrane envelope(s) 4 and feed spacer(s) 14 are spirally wound with collection tube 10 at the axial center. Feed spacers 14 create channels 16 between adjacent membrane sheets 6, allowing feed liquid to pass along the surface of membrane sheets 6.
    [012] When element 1 is placed in a pressure vessel, the feed liquid is supplied under pressure at a feed liquid inlet end 18 and the liquid enters channels 16 formed by the feed spacer 14. feed moves in an axial direction parallel to the collection tube 10. As it moves across the surface of the membrane sheets 6, part of the liquid diffuses under pressure through the membrane sheets 6 and into the permeate sheet 8. This liquid, which contains little or no solute compared to the feed liquid, then moves in a spiral path through the permeate sheet 8 and through holes 12 in the collection tube 10. The liquid moving through collection tube 10 is generally referred to as the permeate or product liquid. The feed liquid which does not diffuse through the membrane sheets 6 continues to move in the axial direction until it reaches an outlet end 20 of element 1. At the outlet end 20 of element 1, the product liquid is removed and the Remaining feed liquid is generally transferred to another spiral wound element 1 to repeat the process to increase the product liquid yield.
    [013] There are several challenges with membrane filtration in general, and particularly for RO filtration. One challenge is the pressure drop along the longitudinal length of the spirally wound element and from one filtration element to the next when connected in series. The feed spacer is a major source of pressure drop due to the fact that it resists the flow of feed liquid through the spiral wound element. As a consequence of this, the supply pressure needs to be increased in the RO filtration system, which increases operating and maintenance costs. A second challenge is fouling, particularly biofouling. Fouling occurs when deposits build up or grow on membranes, which may require increased supply pressure, and can damage or shorten the life of the membranes. Biofouling occurs when deposits are biological in nature, such as bacteria, fungi, protozoa and others. These microorganisms can be deposited and/or can grow on the membrane, reducing efficiency and requiring cleaning. A third challenge is concentration polarization, in which there is an increase in salt concentration at or near the surface of the membrane. This increases the osmotic pressure at the membrane surface and can lead to reduced fluid transmission and increased solute transmission. The feed spacer plays a role in addressing and/or alleviating these concerns.
    [014] Referring to Figures 2 to 4, the present disclosure provides a feed spacer 14 that provides relatively high RO filtration throughput, while addressing issues such as pressure drop, biofouling, and concentration bias. In at least one embodiment, the feed spacer 14 of the present disclosure is formed as an extruded network 30 comprising a first set of filaments 32 and a second set of filaments 34. In at least one embodiment, the filaments of the first set of filaments 32 are arranged parallel to each other and extend in a first direction and the filaments of the second set of filaments 34 are arranged parallel to each other and extend in a second direction generally transverse to the first direction. In at least one embodiment, the first direction and the second direction are substantially perpendicular, such that the first strands 32 and second strands 34 cross at right angles (90°).
    [015] However, it should be understood that the first strands 32 and the second strands 34 may cross at angles other than 90°. In one embodiment, first strands 32 and second strands 34 intersect at angles from 60 to 120 degrees in a direction parallel to a longitudinal axis of the element. In another embodiment, the first filaments 32 and second filaments 34 intersect at angles from 65 to 110 degrees in a direction parallel to a longitudinal axis of the element. In another embodiment, the first filaments 32 and second filaments 34 intersect at angles from 70 to 100 degrees in a direction parallel to a longitudinal axis of the element. In another embodiment, the first strands 32 and second strands 34 intersect at angles from 75 to 90 degrees in a direction parallel to a longitudinal axis of the element.
    [016] In at least one embodiment, the filaments 32 and 34 are elongated extruded polymeric members that traverse and intersect during or shortly after exiting the extrusion die(s) to form the net-like structure. In this embodiment, the filaments 32 and 34 remain on the same side of each other throughout the web 30. However, the filaments 32 and 34 could also be formed from extruded filaments that are braided or woven together rather than crisscrossed during extrusion. Filaments 32 and 34 can be produced from any suitable material, such as polyolefins, polystyrenes, polyesters, polyamides, acetals, fluoropolymers, polyurethanes and elastomers. In at least one embodiment, the filaments 32 and/or 34 are made of polypropylene. In another embodiment, filaments 32 and/or 34 are made of polyethylene, such as low density polyethylene (LDPE), high density polyethylene (HDPE) or ultra high molecular weight polyethylene (UHMWPE). In at least one embodiment, filaments 32 and 34 are made of the same material. In other embodiments, however, it is contemplated that filaments 32 could be made of materials other than filaments 34.
    [017] As shown by way of example in Figures 2 to 4, in at least some embodiments, both sets of filaments 32 and 34 comprise at least two filaments of different size. Each set of filaments 32 and 34 comprises large filaments identified as A and smaller filaments identified as B. Accordingly, the first set of filaments 32 has a plurality of first filaments with a first thickness (filaments A) and a plurality of second filaments with a second thickness (filaments B) and the second set of filaments 34 have a plurality of third filaments with a third thickness (filaments A) and a plurality of fourth filaments with a fourth thickness (filaments B). Filaments A and B can be independently of any suitable size, as long as A is considerably larger than B.
    [018] A feed spacer 14 with both sets of filaments 32, 34 having alternating A and B filaments is now believed to be the most effective configuration for RO spiral wound elements, due to the fact that such a configuration provides a decrease in pressure drop, while still maintaining sufficient support point density with the membrane sheets 6 to maintain the integrity of the channels 16. Furthermore, when both sets of filaments 32, 34 have alternating A and B filaments , the flow through the feed spacer 14 is substantially symmetrical in the channels 16 and exposes each membrane sheet 6 to similar conditions. However, in some embodiments, one set of filaments 32 or filaments 34 may have filaments of uniform thickness, for example, only A filaments or only B filaments, while the other set of filaments 32 or filaments 34 has both A filaments and filaments. B, as described above. In still other embodiments, both or one of filaments 32 and filaments 34 may include filaments that have a third thickness, or C filaments that differ from filaments A and B.
    [019] In one embodiment, the A filaments have a thickness of 0.127 to 1.016 mm (5 to 40 thousandths of an inch or mils). In another embodiment, the A filaments are 0.203 to 0.889 mm (8 to 35 mils) thick. In another embodiment, the A filaments have a thickness of 0.254 to 0.762 mm (10 to 30 mils). In another embodiment, the A filaments have a thickness of 0.381 to 0.635 mm (15 to 25 mils). In yet another embodiment, the A filaments are 0.508 mm (20 mils) thick. In one embodiment, the B filaments are 0.076 to 0.889 mm (3 to 35 mils) thick. In another embodiment, the B filaments have a thickness of 0.076 to 0.635 mm (3 to 25 mils). In another embodiment, the B filaments have a thickness of 0.076 to 0.508 mm (3 to 20 mils). In another embodiment, the B filaments have a thickness of 0.127 to 0.381 mm (5 to 15 mils). In another embodiment, the B filaments are 0.178 to 0.305 mm (7 to 12 mils) thick. In yet another embodiment, the B filaments are 0.254 mm (10 mils) thick. In at least one embodiment, filaments A and filaments B in filaments 32 are the same thickness as filaments A and filaments B in filaments 34. In another embodiment, filaments A of filaments 32 and 34 are of the same thickness and thickness. B filaments have different thicknesses. In another embodiment, the B filaments of filaments 32 and 34 have the same thickness and the A filaments have different thicknesses. In yet another embodiment, both the A filaments and the B filaments of filaments 32 and 34 have different thicknesses.
    [020] In at least one embodiment, the filaments 32 and 34 (A and B) have a circular cross section. However, it is contemplated that any suitable format may be used. When the filaments have a circular cross section, the thickness is measured by measuring the diameter of the filaments 32 and 34. In some embodiments in which the filaments 32 and 34 have a circular cross section, the thickness of the filaments 32 and 34 remains substantially constant. along its entire length. In other embodiments, however, the filaments 32 and 34 may have portions of reduced thickness that fall between the points of intersection 38.
    [021] As can be better seen in Figure 4, the thickness of the net 30 is not uniform, as there are three different types of intersections of filaments 32 and 34: A/A, A/B and B/B. For comparison, a typical prior art feed spacer having uniform filament thickness and uniform overall thickness is shown in Figure 5. An example of a mesh 30 that includes A filaments having a thickness of 0.559 mm (22 mils) and the filaments B which have a thickness of 0.305 mm (12 mils) are shown in cross-section between two sheets of membrane in Figure 6. When two filaments A intersect, the thickness of net 30 is at its maximum and when two filaments B intersect. intersect, the thickness of the net 30 is at its minimum. For use herein, the total thickness of the net 30 refers to the intersections 38 of two A filaments or the maximum thickness of the net 30. In addition, the thickness of the net 30 may not always be twice the thickness of the A filaments. As shown in Figure 4, the two strands can partially join at points of intersection 38, or “penetrate” each other. The amount of fusion of filaments 32 and 34 can vary based on processing parameters. In one modality, it can be from 0.1 to 30%. In another embodiment, the amount of fusion can be from 5 to 20%. In another embodiment, the amount of fusion can be from 10 to 15%. For example, at the 38 intersection of two A filaments, each having a diameter of 0.508 mm (20 mils), the thickness of the mesh 30 might be 0.864 mm (34 mils) instead of 1.016 mm (40 mils, two times the thickness of each filament). In this example, there would be a 15% merge.
    [022] In at least one modality, mesh 30 has a total thickness of 0.508 to 2.032 mm (20 to 80 mils), as measured at intersection points 38. In another modality, mesh 30 has a total thickness of 0.559 to 1,651 mm (22 to 65 mils). In another embodiment, the mesh 30 has a total thickness of 0.635-1.270 mm (25 to 50 mils). In another embodiment, mesh 30 has a total thickness of 0.711 to 1.143 mm (28 to 45 mils). In another embodiment, the mesh 30 has a total thickness of 0.762 to 1.016 mm (30 to 40 mils).
    [023] In the embodiments shown in Figures 2 to 4, each of the filaments 32 and 34 has alternating A and B filaments, that is, the sequence of filaments is ABAB. It is now believed that a sequence of alternating filaments is the most effective sequence for spirally wound elements of RO 1, due to the fact that it provides a more consistent and/or constant flow rate and provides the most effective balance between creating turbulence and supporting channels 16. However, other sequences of filaments are also contemplated, in which multiple A filaments are repeated between B filaments or vice versa (eg ABBABB or AABAAB). Furthermore, the A and B filaments can be arranged in blocks, for example AABB or AAABB. In the embodiments shown in Figures 2 to 4, filaments 32 and 34 have the same filament sequence, however filaments 32 and 34 may have different filament sequences, which can be any combination of those mentioned above.
    [024] The filaments in sets of filaments 32 and 34 can have a uniform spacing between them, which is the filament spacing. Filaments 32 and 34 have the same filament spacing in the embodiments shown in Figures 2 to 4, however, the filament spacing may be different for each set of filaments. Filament spacing can be measured as the number of filaments per 2.54 centimeters (per inch). In at least one embodiment, the filament spacing is from 2 to 30 filaments per inch. In another embodiment, the filament spacing is from 3 to 25 filaments per inch. In another embodiment, the filament spacing is from 5 to 20 filaments per inch. In another embodiment, the filament spacing is from 7 to 15 filaments per inch. In yet another embodiment, the filament spacing is nine filaments per inch. Additionally, it should be understood that openings of varying size 40 formed by the intersection of filaments 32 and 34 can be used. Furthermore, although the holes or openings 40 are shown in the drawings as square, it should be understood that any suitable shape and size could be used. For example, if filaments 32 and 34 are perpendicular and one set of filaments has a smaller filament spacing than the other, rectangular openings 40 can be formed. If filaments 32 and 34 are not perpendicular, then openings 40 may be shaped like a hole.
    [025] The alternating thickness of 32 and 34 filaments, also called alternating filament design, offers improvement over currently available feed spacers in areas such as pressure drop, biofouling, membrane damage and concentration polarization, among others. The advantages discussed below relate to filtering salt water to obtain pure water or drinking water, however, the same principles apply to filtering other feed liquids.
    [026] Alternating filament design (ASD) leads to a reduction in pressure drop compared to a conventional feed spacer which has completely uniform filament thickness. In one embodiment, the pressure drop in a membrane filtration element that has an ASD feed spacer is at least 10% less than the same element that has a conventional feed spacer (i.e., a feed spacer that has filaments of uniform thickness as shown in Figure 5). In another embodiment, the pressure drop in a membrane filtration element that has an ASD feed spacer is at least 15% less than the same element that has a conventional feed spacer. In another embodiment, the pressure drop in a membrane filtration element that has an ASD feed spacer is at least 20% less than the same element that has a conventional feed spacer. In another embodiment, the pressure drop in a membrane filtration element that has an ASD feed spacer is at least 25% less than the same element that has a conventional feed spacer. In another embodiment, the pressure drop in a membrane filtration element that has an ASD feed spacer is at least 30% less than the same element that has a conventional feed spacer. In another embodiment, the pressure drop in a membrane filtration element that has an ASD feed spacer is at least 35% less than the same element that has a conventional feed spacer.
    [027] Without sticking to any particular theory, it is believed that the reduction in pressure drop is due, at least in part, to the reduced filament surface area of the B filaments (compared to conventional feed spacers with all the filaments A). The reduced filament surface area leads to a reduction in form strength, thus helping to reduce the resistance of the net 30 to water flowing over it and across the surface of the membrane sheets 6. The reduction in surface area of total net filament compared to a conventional feed spacer net (i.e., a net with uniform filament thickness) varies based on the thickness of filaments A and B. In at least one embodiment, the filament surface area total network load is reduced by at least 10%. In another embodiment, the total network filament surface area is reduced by at least 25%.
    [028] Another result of the ASD is a reduction in the flow velocity of seawater, or other liquid, compared to conventional feed spacers at the same feed rate. A reduced flow velocity translates to reduced shear stress at the membrane surface and reduced turbulence in salt water. Since shear stress and turbulence are beneficial in addressing problems such as biofouling and concentration polarization (discussed below), it is advantageous to increase the feed rate to drive the flow velocity, shear stress, and turbulence of back to typical levels (ie, those achieved with a typical uniform filament thickness feed spacer). However, the increase in feed rate when the ASD 14 feed spacer is used does not increase the pressure drop to a higher level than the typical spiral wound element. Conversely, the pressure drop may remain less than in the typical element. As a result, an RO filtration system can be operated at a lower feed rate than a typical system, but with the same or less pressure drop and the same or better shear stress and turbulence. Alternatively, the filtration system can be operated at the same feed rate as a typical system, but with a reduced pressure drop. Any mode of operation can therefore result in lower power consumption.
    [029] Biological fouling is the deposition and/or growth of microorganisms on the surface of the membrane, which can result in pressure drop increases, reduced water diffusion through the membrane and an increase in the amount of salt that passes through the membrane. membrane. Biofouling is increased in areas where the feed spacer contacts the membrane. The ASD leads to a reduction in contact area between the feed spacer 14 and the membrane sheets 6 and therefore a reduction in biofouling, due to the fact that the B filaments of filaments 32 and 34 do not come into contact with membrane sheets 6. Typical nets 30 have quite uniform thickness; therefore, each intersection point 38 contacts both adjacent membrane sheets 6. In elements 1 that have networks 30 with an ASD, most of the intersection points 38 contact only one or no adjacent membrane sheets 6 As shown in Figure 4, the intersections 38 of BB filaments come into contact with none of the adjacent membrane sheets 6 and the intersections 38 of AB filaments only come into contact with an adjacent membrane sheet 6. In addition to the reduced contact area with membranes 6, feed spacer 14 with ASD results in lower water velocity in areas where the filaments are thinner. High water velocity is associated with more biofouling growth, due to the fact that more nutrients are carried to the high water velocity areas. The lower water velocity of the ASD 14 feed spacer therefore means that there are less organic nutrients in the B-filament areas, which reduces biofouling in those areas.
    [030] To further reduce biofouling buildup, filaments 32 and 34 can be coated with a low COF coated or can have a low COF additive included in their composition. In one embodiment, the low COF additive is UHMWPE (generally with a molecular weight of 1 to 6 million Da). In another embodiment, the low COF additive is polytetrafluoroethylene (PTFE, also known as Teflon). The low COF additive, if present, may comprise 0.1 to 10% by weight of the feed spacer 14. In another embodiment, the low COF additive may comprise 1 to 7.5% by weight of the feed spacer 14. In another embodiment, the low COF additive can comprise about 5% by weight of the feed spacer 14. The low COF additive can include active or inactive components. In one embodiment, the low COF additive includes 0.1 to 75% by weight of active components. In another embodiment, the low COF additive includes 1 to 50% by weight of active components. In another embodiment, the low COF additive includes 10 to 40% by weight of active components. In another embodiment, the low COF additive includes about 25% by weight of active components. The balance of the low COF additive can be an inactive carrier, such as a carrier resin. The carrier resin can be a polyolefin, for example LDPE, HDPE or polypropylene (PP).
    [031] Decreasing biofouling can reduce the number of membrane cleaning cycles required per year for a membrane filtration element. Chemicals used for cleaning membranes can cause membrane damage, therefore reduced biofouling can also reduce membrane damage. In addition to the reduction of biofouling, the reduced contact area between the feed spacer 14 with ASD and the membrane sheets 6 also reduces membrane damage. The fewer number of intersections 38 that come into contact with the membrane sheets 6 results in less scraping and friction occurring between the feed spacer 14 and the membrane sheets 6.
    [032] Furthermore, due to the reduced pressure drop from the use of the ASD supply spacer 14, the supply spacer 14 can be made thinner than conventional supply spacers for an otherwise similar element 1. If a conventional feed spacer is made thinner or has the same thickness as the ASD feed spacer 14 then there may be unacceptable pressure drop in element 1. Having a thinner feed spacer 14 allows for more membrane envelopes 4 are wrapped around the collection tube 10, thus increasing the amount of surface area of the membrane sheet 6 within the element 1, which typically has a maximum diameter of about 40.64 centimeters (16 inches). Example 1
    [033] Two brackish water reverse osmosis (BWRO) filtration systems were rolled up using ASD feed spacers and compared to two BWRO filtration systems using conventional feed spacers that have uniform thicknesses. The filter elements were 20.32 centimeters (8 inches) in diameter and 101.6 centimeters (40 inches) in length and were tested in parallel, under the conditions shown below in Table 1, for one hour. Both ASD and conventional feed spacers were ~0.86 mm (34 mils) thick and had 25 sheets of membrane and 12 feed spacers. The test results are shown below in Table 2. The rejection rates (eg the percentage of solute prevented from passing through the membrane sheets) for the ASD and conventional feed spacers were similar. Elements that have the ASD power spacer had slightly higher flow rates on a m3 per day basis. The pressure drop (ΔP) of the elements that have the ASD spacer showed an average reduction of about 23.3% compared to the elements that have a traditional spacer.
    Table 1. Test conditions for filtration systems that have ASD, and conventional, supply spacers.
    Table 2. Test results for filtration systems that have ASD and conventional feed spacers. Example 2
    [034] A conventional diamond feed spacer that has a total thickness of 1,905 mm (75 mils) and an ASD feed spacer that has a total thickness of 1,905 mm (75 mils) were manufactured using 3D printing. The conventional feed spacer had a uniform filament thickness of 0.953 mm (37.5 mils). The ASD feed spacer had large filaments (A) with a thickness of 0.953 mm (37.5 mils) and small filaments (B) of 0.476 mm (18.75 mils) (for example, filaments B had a thickness equal to half the thickness of the filament A). The feed spacers were tested using a Sterlitech SEPA CF membrane element cell (“the flow cell”). The conventional spacer and ASD spacer were tested at flow rates of 7.57 and 3.79 liters (2.0 and 1.0 gallons) per minute. The results showed that at a flow rate of 7.57 liters (2.0 gallons)/minute, the ASD spacer had a 16.79% reduction in pressure drop compared to the conventional spacer. For a flow rate of 3.79 liters (1.0 gallon)/minute, the ASD spacer had a 30.05% reduction in pressure drop compared to the conventional spacer. The results are shown below in Table 3.
    Table 3. Pressure drop results in a flow cell for one modality of an ASD supply spacer compared to a conventional spacer. Example 3
    [035] The tests simulated using computational fluid dynamics (CFD) were performed using the Navier-Stokes equations for laminar flow of a Newtonian incompressible liquid. Two conditions were tested: constant inflow rate and constant inflow rate (conditions shown in Table 4, results in Table 5). The simulation results showed that for a constant inlet flow velocity of 0.16 m/s, the pressure drop was reduced by 27% in the ASD supply spacer compared to the conventional spacer. For a constant feed flow rate of 16 l/h, the simulation results showed that the pressure drop was reduced by 32% in the ASD feed spacer compared to the conventional spacer. When the inlet flow velocity was kept constant at 0.16 m/sec, the ASD feed spacer had a 5.9% higher feed flow rate compared to the conventional spacer. When the feed flow rate was kept constant at 16 l/h, the ASD feed spacer had a 5.6% lower inflow velocity compared to the conventional spacer.
    Table 4. CFD conditions for constant input flow velocity and constant feed flow rate simulations.

    Table 5. CFD simulation results for constant input flow velocity and constant feed flow rate simulations.
    [036] Although exemplary embodiments are described above, these embodiments are intended to describe all possible forms of the invention. Preferably, the words used in the descriptive report are descriptive rather than limiting words, and it should be understood that various changes can be made without departing from the spirit and scope of the invention. Additionally, the resources of various embodiments of implementation can be combined to form additional embodiments of the invention.
    权利要求:
    Claims (28)
    [0001]
    1. Spiral wound filtration element (1) CHARACTERIZED in that it comprises: a central collection tube (10) having at least one orifice (12) defined therein; at least one membrane envelope (4) fixed to the central collection tube (10) and having two membrane sheets (6) separated by a spacer (8), the at least one membrane envelope (4) configured to be wound on around the central collection tube (10) to form a spiral; and at least one feed spacer (14) configured to be disposed adjacent to at least one of the two membrane sheets (6) when wrapped around the central collection tube (10) and to create a channel (16) for receiving liquid. to be filtered, the at least one feed spacer (14) configured to allow fluid flow through the membrane envelope (4), the at least one feed spacer (14) comprising a mesh (30) including: a first assembly of solid parallel filaments (32) extending in a first direction and including a plurality of first filaments having a first thickness, and a plurality of solid second filaments having a second thickness that is less than the first thickness, the first and second filaments spaced apart. one another with an open spacing to readily allow fluid flow between the first and second filaments; and a second set of solid parallel filaments (34) fused to the first and second filaments, and extending in a second direction that is transverse to the first set of parallel filaments (32), and including a plurality of third filaments having a third thickness and a plurality of fourth filaments having a fourth thickness that is less than the third thickness, the third and fourth filaments spaced apart from one another with an open spacing to readily allow fluid flow between the third and fourth filaments; wherein the thickness of the at least one feed spacer (14) is not uniform, so that the at least one feed spacer (14) is thicker where the first and third filaments intersect, thinner where the second and fourth filaments intersect, and having an intermediate thickness where the first and fourth filaments intersect and an intermediate thickness where the third and second filaments intersect which is the same as the intermediate thickness where the first and fourth filaments intersect; wherein the first and third strands, the first and fourth strands, the second and fourth strands, and the third and second strands join by 0.1 to 30 percent where each of the first and third strands, the first and fourth strands , the second and fourth strands, and the third and second strands intersect; wherein the total filament surface area is reduced by at least 10 percent relative to having filaments of uniform thickness; and wherein the at least one feed spacer (14) makes contact with the two membrane sheets (6) at contact points and the feed spacer (14) has three thicknesses at contact points: a first thickness and a second thickness greater than the first thickness, and wherein the number of contact points in the second thickness is substantially equal to the sum of contact points of the first thickness.
    [0002]
    2. Spiral-wound filter element (1), according to claim 1, CHARACTERIZED by the fact that the first set of parallel filaments (32) comprises alternating the first and second filaments.
    [0003]
    3. Spiral wound filter element (1), according to claim 1, CHARACTERIZED by the fact that the first set of parallel filaments (32) comprises alternating the first and second filaments and the second set of parallel filaments (34) comprises alternating the third and fourth strands.
    [0004]
    4. Spiral-wound filter element (1), according to claim 1, CHARACTERIZED by the fact that the first filaments and third filaments have thicknesses from 0.127 to 1.016 millimeters (5 to 40 mils) and the second filaments and the fourth filaments are 0.076 to 0.889 millimeters (3 to 35 mils) thick.
    [0005]
    5. Spiral-wound filter element (1), according to claim 1, CHARACTERIZED by the fact that the first filaments and third filaments have thicknesses from 0.203 to 0.889 millimeters (8 to 35 mils) and the second filaments and the fourth filaments are 0.127 to 0.381 millimeters thick (5 to 15 mils).
    [0006]
    6. Spiral-wound filter element (1), according to claim 1, CHARACTERIZED by the fact that the first filaments and third filaments have thicknesses from 0.254 to 0.762 millimeters (10 to 30 mils) and the second filaments and the fourth filaments are 0.178 to 0.305 millimeters (7 to 12 mils) thick.
    [0007]
    7. Spiral wound filter element (1), according to claim 1, CHARACTERIZED by the fact that the first filaments and third filaments have the same thickness and the second filaments and fourth filaments have the same thickness.
    [0008]
    8. Spiral wound filter element (1), according to claim 1, CHARACTERIZED by the fact that the at least one feed spacer (14) has a full thickness at an intersection (38) of the first and third filaments filaments from 0.635 to 1.27 millimeters (25 to 50 mils).
    [0009]
    9. Spiral-wound filter element (1), according to claim 1, CHARACTERIZED by the fact that the first set of parallel filaments (32) is perpendicular to the second set of parallel filaments (34).
    [0010]
    10. Spiral wound filter element (1) according to claim 1, CHARACTERIZED by the fact that the first set of parallel filaments (32) crosses the second set of parallel filaments (34) at an angle of 65 to 110 degrees in a direction parallel to a longitudinal geometric axis of the spirally wound filter element (1).
    [0011]
    11. Spiral-wound filter element (1), according to claim 1, CHARACTERIZED by the fact that a pressure drop of the fluid flow through the spiral-wound filter element (1) is reduced by at least 10% compared to a same spirally wound filter element (1) having a feed spacer (14) with filaments having substantially identical thicknesses.
    [0012]
    12. Spiral wound filter element (1), according to claim 1, CHARACTERIZED by the fact that the at least one feed spacer (14) includes from 0.1 to 10% by weight of polyethylene by weight ultra-high molecular.
    [0013]
    13. Extruded mesh (30) for a spirally wound filter element (1), as defined in any one of claims 1 to 12, CHARACTERIZED by the fact that it comprises: a first set of parallel filaments (32) extending in a first direction and including a plurality of first filaments having a first thickness and a plurality of second filaments having a second thickness that is less than the first thickness; and a second set of parallel filaments (34) extending in a second direction that is transverse to the first direction and including a plurality of third filaments having a third thickness and a plurality of fourth filaments having a fourth thickness that is less than the third thickness ; wherein the first set of filaments and the second set of filaments are always located on the same side of each other; and the first set of parallel filaments (32) comprises alternating the first and second filaments, and the second set of parallel filaments (34) comprises alternating the third and fourth filaments; where the thickness of the net is not uniform, so that the net (30) is thicker where the first and third strands intersect, thinner where the second and fourth strands intersect, and having an intermediate thickness where the first and fourth strands intersect and an intermediate thickness where the third and second strands intersect which is the same as the intermediate thickness where the first and fourth strands intersect.
    [0014]
    14. Extruded network (30), according to claim 13, CHARACTERIZED by the fact that it additionally comprises from 0.1 to 10% by weight of ultra-high molecular weight polyethylene.
    [0015]
    15. Extruded net (30) according to claim 13, CHARACTERIZED by the fact that the first filaments and third filaments have thicknesses from 0.127 to 1.016 millimeters (5 to 40 mils) and the second filaments and fourth filaments have thicknesses from 0.076 to 0.889 millimeters (3 to 35 mils).
    [0016]
    16. Extruded net (30) according to claim 13, CHARACTERIZED by the fact that the first filaments and third filaments have thicknesses from 0.203 to 0.889 millimeters (8 to 35 mils) and the second filaments and fourth filaments have thicknesses from 0.127 to 0.381 millimeters (5 to 15 mils).
    [0017]
    17. Extruded net (30) according to claim 13, CHARACTERIZED by the fact that the net (30) has a total thickness at an intersection of the first (32) and second (34) set of parallel filaments from 0.635 to 1 .27 millimeters (25 to 50 mils).
    [0018]
    18. Extruded net (30) according to claim 13, CHARACTERIZED by the fact that the first set of parallel filaments (32) crosses the second set of parallel filaments (34) at an angle of 65 to 110 degrees in one direction parallel to a longitudinal geometric axis of a spirally wound filter element (1).
    [0019]
    19. Spiral wound filtration element (1) CHARACTERIZED in that it comprises: a central collection tube (10) having at least one orifice (12) defined therein; at least one membrane envelope (4) fixed to the central collection tube (10) and having two membrane sheets (6) separated by a spacer (8), the at least one membrane envelope (4) configured to be wound on around the central collection tube (10) to form a spiral; and at least one feed spacer (14) disposed adjacent to at least one membrane sheet of the two membrane sheets (6) when wrapped around the central collection tube (10) and to create a channel (16) for receiving liquid to be filtered, the at least one feed spacer (14) comprising a mesh (30) including: a first set of parallel filaments (32) extending in a first direction and including a plurality of first filaments having a first thickness and a plurality of second filaments having a second thickness that is less than the first thickness; and a second set of parallel filaments (34) extending in a second direction that is transverse to the first direction and including a plurality of third filaments having a third thickness and a plurality of fourth filaments having a fourth thickness that is less than the third thickness ; wherein the first set of parallel filaments (32) and the second set of parallel filaments (34) form opposite faces of the at least one feed spacer (14); and wherein the thickness of the at least one feed spacer (14) is not uniform, so that the at least one feed spacer (14) is thicker where the first and third strands intersect, thinner where the second and fourth filaments intersect, and having an intermediate thickness where the first and fourth filaments intersect and an intermediate thickness where the third and second filaments intersect which is the same as the intermediate thickness where the first and fourth filaments intersect.
    [0020]
    20. Spiral wound filtration element (1) CHARACTERIZED in that it comprises: a central collection tube (10) having at least one orifice (12) defined therein; at least one membrane envelope (4) fixed to the central collection tube (10) and having two membrane sheets (6) separated by a spacer (8), the at least one membrane envelope (4) configured to be wound on around the central collection tube (10) to form a spiral; and at least one feed spacer (14) configured to be disposed adjacent to at least one membrane sheet of the two membrane sheets (6) when wrapped around the central collection tube (10) and to create a channel (16) for receiving liquid to be filtered, the at least one feed spacer (14) being capable of having a substantially flat shape which is wound in a spiral orientation when inside the spiral wound filter element (1), the at least one spacer feeder (14) comprising a net (30) including: a first set of parallel filaments (32) extending in a first direction and including a plurality of first filaments having a first thickness and a plurality of second filaments having a second thickness that is less than the first thickness; and a second set of parallel filaments (34) extending in a second direction that is transverse to the first set of parallel filaments (32), and including a plurality of third filaments having a third thickness and a plurality of fourth filaments having a fourth thickness which is less than the third thickness; wherein the first and third filaments are fused together in fused areas at intervals along the at least one feed spacer (14), and the second and fourth filaments are fused together in fused areas at intervals alternating diagonally with the first and third filaments.
    [0021]
    21. Spiral wound filter element (1) according to claim 20, CHARACTERIZED by the fact that the second and third filaments are fused together in fused areas spaced at intervals and the first and fourth filaments are fused to each other others in fused areas spaced at intervals.
    [0022]
    22. Spiral-wound filtration element (1), according to claim 21, CHARACTERIZED by the fact that the fused areas of the first and third filaments; the fused areas of the second and fourth filaments; and the fused areas of the first and fourth filaments are all coplanar when the at least one feed spacer (14) is unwound.
    [0023]
    23. Spiral wound filter element (1), according to claim 20, CHARACTERIZED by the fact that the first strands, second strands, third strands, and fourth strands are substantially linear in shape when the at least one feed spacer (14) is unrolled; wherein at least one of the two membrane sheets (6) forming the at least one membrane envelope (4) makes contact with the at least one feed spacer (14) mainly along the first filaments, and a second membrane sheet the two membrane sheets (6) make contact with at least one feed spacer (14) mainly along the third filaments; wherein nodes where the first set of parallel filaments (32) and the second set of parallel filaments (34) of the at least one feed spacer (14) meet have a first thickness that is less than or equal to the combined thickness of the first and third filaments; and a second thickness equals the combined thickness of the second and fourth filaments.
    [0024]
    24. Spiral wound filtration element (1), according to claim 20, CHARACTERIZED by the fact that the first, second, third and fourth filaments are coextruded.
    [0025]
    25. Spiral wound filter element (1), according to claim 24, CHARACTERIZED by the fact that the maximum thickness of the at least one feed spacer (14) is less than or equal to the thickness of the first and third filaments .
    [0026]
    26. Spiral-wound filter element (1), according to claim 25, CHARACTERIZED by the fact that the maximum thickness of the at least one feed spacer (14) is twice the thickness of the first filaments; and wherein the maximum thickness of the at least one feed spacer (14) is approximately twice the thickness of the third filaments.
    [0027]
    27. Spiral wound filter element (1), according to claim 20, CHARACTERIZED by the fact that the highest surface on a first face of the at least one feed spacer (14) is defined by the first filaments; and the lower surface on a second face of the at least one feed spacer (14) is defined by the third filaments.
    [0028]
    28. Spiral wound filtration element (1) according to claim 1, CHARACTERIZED by the fact that the first filaments have a first edge that is substantially flat with the top of the at least one feed spacer (14) when the at least one feed spacer (14) is unrolled, but an opposite edge which is not substantially flat with the bottom of the at least one feed spacer (14) when the at least one feed spacer (14) is unwound; the third filaments having a first edge that is substantially flat with the bottom of the at least one feed spacer (14) when the at least one feed spacer (14) is unwound, but an opposite edge that is not substantially flat with the top of the at least one feed spacer (14) when the at least one feed spacer (14) is unwound.
    类似技术:
    公开号 | 公开日 | 专利标题
    BR112014032391B1|2021-08-10|SPIRAL WRAPPED FILTRATION ELEMENTS AND EXTRUDED NET
    JP4119425B2|2008-07-16|A spirally wound member with an improved supply spacer
    Sreedhar et al.2018|3D printed feed spacers based on triply periodic minimal surfaces for flux enhancement and biofouling mitigation in RO and UF
    US10159926B2|2018-12-25|Tunable nanofiber filter media and filter devices
    JP6235119B2|2017-11-22|Osmosis equipment
    JP2015205269A|2015-11-19|Separation membrane structure and separation membrane element
    US20130146531A1|2013-06-13|Feed spacers for spiral wound membrane element
    US11065580B2|2021-07-20|Separation membrane element
    Dumée et al.2015|Next generation membranes for membrane distillation and future prospects
    JP2009028714A|2009-02-12|Spiral separating membrane element
    JP6693027B2|2020-05-13|Reverse osmosis filter module
    US20210205761A1|2021-07-08|Flow path spacer and spiral membrane element
    JP2013212456A|2013-10-17|Hollow fiber membrane module
    KR102104160B1|2020-04-23|Four-layered feed spacer
    WO2017105356A1|2017-06-22|Hollow fiber membrane module
    CN111801152A|2020-10-20|Membrane separation system and method for operating membrane separation system
    JPWO2018021387A1|2019-05-16|Separation membrane element
    JP2019198847A|2019-11-21|Flow channel spacer and spiral type membrane element
    Ghotbi et al.2018|Numerical investigation of UF membrane to reduce energy consumption using double porosity approach
    JP2019198848A|2019-11-21|Flow channel spacer and spiral type membrane element
    WO2014206381A1|2014-12-31|The asymmetric ion-exchange membrane and use thereof
    JP2018015735A|2018-02-01|Separation membrane element
    WO2017175137A1|2017-10-12|Fouling resistant membrane spacers
    同族专利:
    公开号 | 公开日
    US10035106B2|2018-07-31|
    EP2864026A4|2016-04-06|
    ES2674071T3|2018-06-27|
    KR102085394B1|2020-03-05|
    US20190111396A1|2019-04-18|
    BR112014032391A2|2017-06-27|
    WO2014004142A1|2014-01-03|
    CN104411385B|2018-07-20|
    KR20150036192A|2015-04-07|
    US11084198B2|2021-08-10|
    PL2864026T3|2018-11-30|
    EP2864026B1|2018-03-21|
    JP6242887B2|2017-12-06|
    US20130341264A1|2013-12-26|
    IN2014DN11117A|2015-09-25|
    CN104411385A|2015-03-11|
    EP2864026B8|2018-11-07|
    JP2015526282A|2015-09-10|
    EP2864026A1|2015-04-29|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    CA1101332A|1976-01-30|1981-05-19|Edward Shanbrom|Simplified method for preparation of high yield, highpurity factor viii concentrate|
    SE430852B|1977-11-18|1983-12-19|Gambro Lundia Ab|DEVICE FOR SEPARATION BY SEMIPERMEABLA MEMBRAN|
    US4778601A|1984-10-09|1988-10-18|Millipore Corporation|Microporous membranes of ultrahigh molecular weight polyethylene|
    US4710185A|1985-09-12|1987-12-01|Kimberly-Clark Corporation|Foraminous net cover for absorbent articles|
    ZA866656B|1985-09-12|1987-04-29|Kimberly Clark Co|Foraminous net cover for absorbent articles|
    US5236665A|1988-10-20|1993-08-17|Baxter International Inc.|Hollow fiber treatment apparatus and membrane oxygenator|
    US5096584A|1990-01-29|1992-03-17|The Dow Chemical Company|Spiral-wound membrane separation device with feed and permeate/sweep fluid flow control|
    US5069793A|1990-09-12|1991-12-03|Membrane Technology & Research, Inc.|Membrane module|
    US5180409A|1992-01-30|1993-01-19|Minnesota Mining And Manufacturing Company|Hot-gas-filtering fabric of spaced uncrimped support strands and crimped lofty fill yarns|
    JP3875288B2|1995-07-28|2007-01-31|インテグリス・インコーポレーテッド|Cartridge filtration device|
    CN1137763C|1998-06-18|2004-02-11|东丽株式会社|Spiral reverse osmosis membrane element, reverse osmosis membrane module using it, device and method for reverse osmosis separation incorporating module|
    US6068771A|1999-02-11|2000-05-30|Koch Membrane Systems, Inc.|Method for sealing spiral wound filtration modules|
    JP2000237554A|1999-02-18|2000-09-05|Nitto Denko Corp|Spiral type membrane element|
    US6881336B2|2002-05-02|2005-04-19|Filmtec Corporation|Spiral wound element with improved feed space|
    JP2004283708A|2003-03-20|2004-10-14|Nitto Denko Corp|Spiral separation membrane element|
    JP3998142B2|2003-03-20|2007-10-24|日東電工株式会社|Spiral type separation membrane element|
    CN100522325C|2004-03-26|2009-08-05|日东电工株式会社|Spiral type separation membrane element|
    JP4688140B2|2004-03-26|2011-05-25|日東電工株式会社|Spiral type separation membrane element|
    US8182694B2|2004-04-08|2012-05-22|Natrix Separations Inc.|Membrane stacks|
    TWI262097B|2005-01-28|2006-09-21|Univ Chung Yuan Christian|Feed spacer for spiral-wound membrane module abstract of the invention|
    CN2774624Y|2005-02-25|2006-04-26|佳尼特纯水设备有限公司|Screw roll type film element|
    US7749661B2|2007-01-31|2010-07-06|Gm Global Technology Operations, Inc.|High performance, compact and low pressure drop spiral-wound fuel cell humidifier design|
    EP2008705A1|2007-06-29|2008-12-31|Friesland Brands B.V.|Spiral wound filter assembly|
    JP5231362B2|2008-09-09|2013-07-10|日東電工株式会社|Supply side channel material and spiral separation membrane element|
    JP2011109811A|2009-11-17|2011-06-02|Canon Inc|Power supply device, heating device using the same, and image forming device|
    PL2864026T3|2012-06-26|2018-11-30|Swm Luxembourg S A R L|Membrane filtration using low energy feed spacer|PL2864026T3|2012-06-26|2018-11-30|Swm Luxembourg S A R L|Membrane filtration using low energy feed spacer|
    US9860504B2|2015-01-09|2018-01-02|Vixs Systems, Inc.|Color gamut mapper for dynamic range conversion and methods for use therewith|
    US20180071688A1|2015-02-23|2018-03-15|Christopher James Zwettler|Spacer for membrane separation|
    CN104843912B|2015-05-11|2020-03-13|艾欧史密斯（南京）水处理产品有限公司|Filter device and cleaning method thereof|
    CN105233693B|2015-11-13|2018-01-16|珠海格力电器股份有限公司|A kind of water purifier and its reverse-osmosis membrane element|
    US10166513B2|2015-12-18|2019-01-01|Nanyang Technological University|Spacer for a membrane module|
    US10348120B2|2016-05-10|2019-07-09|Kam Yuen Kan|System and method for charging of electric vehicle|
    JP6353957B2|2016-11-18|2018-07-04|日東電工株式会社|Raw water channel spacer and spiral membrane element provided with the same|
    ES2596237B2|2016-12-01|2017-07-07|Universitat Politècnica De València|MEMBRANE MODULE FOR FLUID TREATMENT AND MANUFACTURING PROCEDURE OF A MEMBRANE MODULE|
    WO2018222746A1|2017-05-30|2018-12-06|Conwed Plastics Llc|Membrane separation spacer with low contact angle|
    KR102157928B1|2017-10-20|2020-09-18|주식회사 엘지화학|Three-layered feed spacer and reverse osmosis filter module for water treatment comprising the same|
    KR102230979B1|2017-12-12|2021-03-23|주식회사 엘지화학|Feed spacer and reverse osmosis filter module for water treatment comprising the same|
    WO2019117479A1|2017-12-12|2019-06-20|주식회사 엘지화학|Feed spacer and reverse osmosis filter module including same|
    KR102036995B1|2018-05-03|2019-11-26|한국과학기술연구원|Piezoelectric separator with improved watertightness|
    JP2019198849A|2018-05-18|2019-11-21|日東電工株式会社|Flow channel spacer and spiral type membrane element|
    JP2019198847A|2018-05-18|2019-11-21|日東電工株式会社|Flow channel spacer and spiral type membrane element|
    US20190388843A1|2018-06-25|2019-12-26|Magna Imperio Systems Corp.|3d printed spacers for ion-exchange device|
    KR102129667B1|2018-08-09|2020-07-02|도레이첨단소재 주식회사|Filter assembly containing mesh sheet for internal spacer for water treatment and filter module containing the same|
    US20210379536A1|2018-10-30|2021-12-09|Aqua Membranes, Inc.|Flow Separators for Spiral Wound Elements|
    JP2021184984A|2019-08-30|2021-12-09|東レ株式会社|Separation membrane element|
    CN113244773A|2021-06-17|2021-08-13|湖南澳维新材料技术有限公司|Concentrated water separation net for roll type membrane element|
    法律状态:
    2018-03-06| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2018-03-13| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2018-03-20| B06I| Publication of requirement cancelled [chapter 6.9 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |
    2019-02-12| B25A| Requested transfer of rights approved|Owner name: SWM LUXEMBOURG S.A.R.L. (LU) |
    2019-10-01| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2021-03-16| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|
    2021-07-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-08-10| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/06/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    US201261690419P| true| 2012-06-26|2012-06-26|
    US61/690,419|2012-06-26|
    PCT/US2013/046101|WO2014004142A1|2012-06-26|2013-06-17|Membrane filtration using low energy feed spacer|
    [返回顶部]